PCB Analysis refers to testing for Polychlorinated Biphenyls (PCBs) – toxic, persistent chemicals that were once commonly used in transformer oil and other electrical equipment due to their chemical stability and non-flammability.
What Are PCBs?
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PCBs are synthetic organic chemicals with chlorinated compounds.
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Used in transformer oils, capacitors, and other electrical gear until the 1970s–80s.
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Banned or restricted in most countries due to their toxic and carcinogenic properties, and because they bioaccumulate in the environment.
Why Test Transformer Oil for PCBs?
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Regulatory compliance (e.g. EPA, IEC, OSHA)
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Environmental protection
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Worker safety
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Determine disposal method (hazardous or non-hazardous waste)
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Identify contaminated transformers that need decontamination or replacement
PCB Analysis Methods
Method | Description |
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Gas Chromatography (GC) | Most common; separates and measures PCB concentrations |
Gas Chromatography-Mass Spectrometry (GC-MS) | More sensitive; used for very low-level detection |
Immunoassay (Screening) | Quick field tests; less accurate, used for screening |
EPA Method 8082A | Standard method for PCB detection in oil samples |
PCB Concentration Levels
Concentration (ppm) | Classification |
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< 2 ppm | Non-PCB |
2 – 50 ppm | PCB-Contaminated |
> 50 ppm | PCB (hazardous) |
How to Collect Samples for PCB Testing
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Wear proper PPE (gloves, goggles, protective clothing)
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Use clean, solvent-rinsed glass bottles
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Label the bottle clearly (ID, date, location)
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Take samples from bottom valve or oil sampling port
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Seal tightly, and send to accredited lab within 48 hours (if possible)
Test Report Includes
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PCB concentration (in ppm or mg/kg)
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Analytical method used (e.g. EPA 8082A)
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Sample ID, source, and date
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Interpretation (Non-PCB, PCB-Contaminated, or PCB)
If PCB is Detected
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Equipment may need labeling, decontamination, or special disposal
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Oil with >50 ppm must be handled as hazardous waste
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Follow national regulations (e.g. U.S. TSCA regulations, IEC 61619)